It's one of those annoying little bits of "scientific trivia" that's just not true. But where did the idea come from?
In medieval European cathedrals, the glass panes sometimes are thicker at the bottom than they are at the top, giving the appearance that the seemingly solid glass has melted. This observation influenced internet trivia sites and even high school chemistry teachers to say that glass is actually a supercooled liquid.
Glass, however, is actually neither a liquid nor a solid. It is an amorphous solid—a state somewhere between those two states of matter.
Solids are highly organized structures. They include crystals, like sugar and salt, with their millions of atoms lined up in a row. Glasses, though more organized than liquids, do not attain the rigid order of crystals. Amorphous means the atoms don’t exhibit that long-range order.
When glass is made, the material is quickly cooled from its liquid state but does not solidify when its temperature drops below its melting point. At this stage, the material is a supercooled liquid, an intermediate state between liquid and glass. To become an amorphous solid, the material is cooled further, below the glass-transition temperature. Past this point, the molecular movement of the material's atoms has slowed nearly to a stop and the material is now a glass. For practical purposes, glass is like a solid although a disorganized one.
Over long periods of time, the molecules making up the glass shift themselves to settle into a more stable, crystal-like formation. The closer the glass is to its glass-transition temperature, the more it shifts; the further away from that changeover point, the slower its molecules move and the more solid it seems.
Note to cathedral tour guides everywhere: Some medieval glass panes are thicker on the bottom due to how the glass was made. At that time, glassblowers flattened glass cylinders to make panes of glass. The panes often were not uniformly flat and workers installing the windows preferred, for whatever reason, to put the thicker sides of the pane at the bottom.
Source: Scientific American, February 2007